TiAlN/Cr、TiAlN/CrN和TiAlN/CrAlN多层涂层的热盐腐蚀行为

兰州理工大学学报 ›› 2023, Vol. 49 ›› Issue (4): 1-10.

• 材料科学与工程 • 下一篇

TiAlN/Cr、TiAlN/CrN和TiAlN/CrAlN多层涂层的热盐腐蚀行为

何泽年^1,2, 王顺花^*1, 蒲吉斌²

1.兰州交通大学材料科学与工程学院, 甘肃兰州 730070;
2.中国科学院宁波材料技术与工程研究所, 海洋新材料与应用技术重点实验室, 浙江宁波 315201

收稿日期:2023-01-03 出版日期:2023-08-28 发布日期:2023-08-29
通讯作者: 王顺花(1967-),女,甘肃兰州人,教授. Email:wangsh@mail.lzjtu.cn
基金资助:
国家重点研发计划(2020B2010401YF)

Hot salt corrosion behavior of TiAlN/Cr、TiAlN/CrN and TiAlN/CrAlN multilayer coatings

HE Ze-nian^1,2, WANG Shun-hua¹, PU Ji-bin²

1. School of Materials Science and Engineering,Lanzhou Jiaotong University, Lanzhou 730070, China;
2. Key Laboratory of Marine Materials and Related Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences,Ningbo 315201, China

Received:2023-01-03 Online:2023-08-28 Published:2023-08-29

摘要/Abstract

摘要： 钛合金的热盐腐蚀问题已引起人们的广泛关注,金属氮化物防护涂层是延长钛合金服役寿命的有效途径.采用多弧离子镀技术在钛合金表面沉积了TiAlN/Cr涂层、TiAlN/CrN涂层、TiAlN/CrAlN-5涂层和TiAlN/CrAlN-10涂层.通过扫描电子显微镜(SEM)、能量色散谱仪(EDS)、X射线衍射仪(XRD)、划痕测试仪、3D激光显微镜等测试手段对比研究了4种多层涂层的热盐腐蚀行为,分析了涂层热盐腐蚀前后的微观形貌和物相成分.结果表明:Al元素的添加和调制周期的优化可以提高涂层的致密性,改善涂层表面质量.其中TiAlN/CrAlN-10多层涂层由于界面密度高,表现出优异的耐热盐腐蚀性能.

关键词: 热盐腐蚀, TiAlN/CrAlN涂层, 界面密度, 耐腐蚀性能

Abstract: The hot salt corrosion of titanium alloys has attracted extensive attention. Metal nitride protective coating is an effective way to extend the service life of titanium alloys. In this study, the TiAlN/Cr coating, TiAlN/CrN coating, TiAlN/CrAlN-5 coating and TiAlN/CrAlN-10 coating were deposited on titanium alloy surface by Multi-arc Ion Plating technology. The differences in hot salt corrosion behavior of four kinds of multilayer coatings were compared by Scanning Electron Microscope (SEM), Energy Dispersion analyzer (EDS), X-ray diffractometer (XRD), Scratch tester and 3D Laser Microscope. Meanwhile, the microstructure and phase composition of the coatings were analyzed before and after hot salt corrosion. The results indicated that the addition of Al element and the optimization of modulation period can improve the surface quality of the coating. Among them, TiAlN/CrAlN-10 multilayer coating shows excellent heat resistance to salt corrosion due to its high interface density.

Key words: hot salt corrosion, TiAlN/CrAlN coating, interface density, corrosion resistance

中图分类号:

TG174.4

何泽年, 王顺花, 蒲吉斌. TiAlN/Cr、TiAlN/CrN和TiAlN/CrAlN多层涂层的热盐腐蚀行为[J]. 兰州理工大学学报, 2023, 49(4): 1-10.

HE Ze-nian, WANG Shun-hua, PU Ji-bin. Hot salt corrosion behavior of TiAlN/Cr、TiAlN/CrN and TiAlN/CrAlN multilayer coatings[J]. Journal of Lanzhou University of Technology, 2023, 49(4): 1-10.

参考文献

[1] BOYER R R.An overview on the use of titanium in the aerospace industry [J].Materials Science and Engineering A,1996,213:103-114.
[2] ZHOU Y G,ZENG W D,YU H Q.An investigation of a new near-beta forging process for titanium alloys and its application in aviation components [J].Materials Science and Engineering A,2005,393:204-212.
[3] 杨文涛,隆小庆.飞机上钛合金的特殊腐蚀形式 [J].全面腐蚀控制,2008,2:42-45,26.
[4] 喻利花,董松涛,钟春良,等.磁控溅射Ti_1－xAl_xN薄膜的微结构及性能研究 [J].金属热处理,2008,11:55-58.
[5] PETERSEN V C.Hot salt stress corrosion of titanium-a review of the problem and methods for improving the resistance of titanium [J].J Met,1971,23(4):40-47.
[6] 孙志杰,王洋.钛合金应力腐蚀研究现状及展望 [J].材料开发与应用,2020,35(2):94-100.
[7] SHI H,LIU D,ZHANG X,et al.Effect of pre-hot salt corrosion on hot salt corrosion fatigue behavior of the TC11 titanium alloy at 500 ℃ [J].International Journal of Fatigue,2022,163:107055.
[8] CISZAK C,POPA I,BROSSARD J-M,et al.NaCl induced corrosion of Ti-6Al-4V alloy at high temperature [J].Corrosion Science,2016,110:91-104.
[9] LEE C M,HAN Y-S,JEONG J S,et al.Effect of pre-strain on oxidation behaviour of nickel-based superalloys in air at 700 ℃ [J].Corrosion Science,2022,200:110229.
[10] GUO H,SUN Q,ZHOU D,et al.Erosion behavior of CrN,CrAlN and CrAlN/CrN multilayer coatings deposited on Ti6Al4V [J].Surface and Coatings Technology,2022,437:128284.
[11] MA J,JIANG S M,GONG J,et al.Hot corrosion properties of composite coatings in the presence of NaCl at 700 and 900 ℃ [J].Corrosion Science,2013,70:29-36.
[12] CHIM Y C,DING X Z,ZENG X T,et al.Oxidation resistance of TiN,CrN,TiAlN and CrAlN coatings deposited by lateral rotating cathode arc [J].Thin Solid Films,2009,517(17):4845-4849.
[13] YANG W,XIONG J,GUO Z,et al.Structure and properties of PVD TiAlN and TiAlN/CrAlN coated Ti(C,N)-based cermets [J].Ceramics International,2017,43(2):1911-1915.
[14] DENG J,WU F,LIAN Y,et al.Erosion wear of CrN,TiN,CrAlN,and TiAlN PVD nitride coatings [J].International Journal of Refractory Metals and Hard Materials,2012,35:10-16.
[15] BEN HASSINE M,ANDRéN H-O,IYER A H S,et al.Growth model for high-Al containing CVD TiAlN coatings on cemented carbides using intermediate layers of TiN [J].Surface and Coatings Technology,2021,421:127361.
[16] ZHANG M,XIN L,DING X,et al.Effects Ti/TiAlN composite multilayer coatings on corrosion resistance of titanium alloy in solid NaCl-H₂O-O₂ at 600 ℃ [J].Journal of Alloys and Compounds,2018,734:307-317.
[17] SHUGUROV A R,KUZMINOV E D.Mechanical and tribological properties of Ti-Al-Ta-N/TiAl and Ti-Al-Ta-N/Ta multilayer coatings deposited by DC magnetron sputtering [J].Surface and Coatings Technology,2022,441:128582.
[18] LI R,CHENG C,PU J.NaCl-induced hot-corrosion behavior of TiAlN single-layer and TiAlN/Ti multilayer coatings at500 ℃ [J].Materials Today Communications,2022,33:104421.
[19] WANG L,WANG M,CHEN H.Corrosion mechanism investigation of TiAlN/CrN superlattice coating by multi-arc ion plating in 3.5 wt % NaCl solution [J].Surface and Coatings Technology,2020,391:125660.
[20] WADSWORTH I J S,DONOHUE L A,MIINZ W D.Thermal stability and oxidation resistance of TiAlN-CrN multilayer coatings [J].Surface and Coatings Technology,1997,94/95:315-321.
[21] LI R,WANG S,ZHOU D,et al.A new insight into the NaCl-induced hot corrosion mechanism of TiN coatings at 500 ℃ [J].Corrosion Science,2020,174:108794.
[22] LI R,WANG S,PU J,et al.Study of NaCl-induced hot-corrosion behavior of TiN single-layer and TiN/Ti multilayer coatings at 500 ℃ [J].Corrosion Science,2021,192:109838.
[23] 陈彦军,王顺花,蒲吉斌,等.多弧离子镀制备氮化铬基涂层及其摩擦学性能研究 [J].西北师范大学学报(自然科学版),2020,56(3):48-54,109.
[24] 余春燕,王社斌,尹小定,等.CrAlN薄膜高温抗氧化性的研究 [J].稀有金属材料与工程,2009,38(6):1015-1018.
[25] XIA B,ZHOU S,WANG Y,et al.Multilayer architecture design to enhance load-bearing capacity and tribological behavior of CrAlN coatings in seawater [J].Ceramics International,2021,47(19):27430-27440.
[26] CHEN X,GAO H,BAI Y,et al.Thermal failure mechanism of multilayer brittle TiN/CrAlN films [J].Ceramics International,2018,44(7):8138-8144.

TiAlN/Cr、TiAlN/CrN和TiAlN/CrAlN多层涂层的热盐腐蚀行为

Hot salt corrosion behavior of TiAlN/Cr、TiAlN/CrN and TiAlN/CrAlN multilayer coatings

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 6

编辑推荐

Metrics

本文评价

[1]	边春华, 杨伟杰, 张维, 李邱达, 文杰, 冯力. FeCr相与AlCo相在AlCoCrCuFeNi高熵合金涂层摩擦过程中的作用分析[J]. 兰州理工大学学报, 2023, 49(2): 9-16.
[2]	孙永江, 张金玲, 翟海民, 王海鹏, 李文生. Zn-Al冷喷涂复合涂层耐3.5 wt.%NaCl溶液腐蚀行为[J]. 兰州理工大学学报, 2023, 49(2): 17-23.
[3]	安国升, 李文生, 冯力, 成波, 李子钰, 周兰. 粘接层预氧化对热障涂层TGO生长与抗高温氧化性能的影响[J]. 兰州理工大学学报, 2022, 48(6): 1-7.
[4]	隋然, 居春艳, 贾金龙, 赵丹. Ti对Sn-xTi/Al₂O₃润湿性的影响[J]. 兰州理工大学学报, 2020, 46(4): 15-21.
[5]	兰晔峰, 王创造, 胡秋晨, 胡巍巍, 李庆林. 奥氏体不锈钢离子渗N组织及性能[J]. 兰州理工大学学报, 2020, 46(1): 7-12.
[6]	李庆林, 赵尚, 胡秋晨, 胡巍巍, 兰晔峰. 316奥氏体不锈钢渗N/镀CrN复合改性层组织与性能[J]. 兰州理工大学学报, 2020, 46(1): 13-19.