Ni-Mo-Y-CaF2高温自润滑复合材料的制备与摩擦学性能

兰州理工大学学报 ›› 2024, Vol. 50 ›› Issue (6): 1-10.

• 材料科学与工程 • 下一篇

Ni-Mo-Y-CaF₂高温自润滑复合材料的制备与摩擦学性能

苏霄鹏¹, 金伟文^*2, 杨贵荣¹, 陆龙², 王静波³

1.兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室, 甘肃兰州 730050;
2.兰州工业研究院, 甘肃兰州 730050;
3.中国科学院兰州化学物理研究所固体润滑国家重点实验室, 甘肃兰州 730000

收稿日期:2023-10-07 出版日期:2024-12-28 发布日期:2025-01-13
通讯作者: 金伟文(1970-),男,浙江东阳人,工程师.Email:66962226@qq.com
基金资助:
兰州市科技计划项目(2019-1-17)

Preparation and tribological properties of Ni-Mo-Y-CaF₂ high temperature self-lubricating composites

SU Xiao-peng¹, JIN Wei-wen², YANG Gui-rong¹, LU Long², WANG Jing-bo³

1. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou Univ. of Tech., Lanzhou 730050, China;
2. Lanzhou Institute of Industry Research, Lanzhou 730050, China;
3. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Received:2023-10-07 Online:2024-12-28 Published:2025-01-13

摘要/Abstract

摘要： 采用放电等离子烧结(SPS)技术制备了不同CaF₂添加量的Ni-Mo-Y-CaF₂高温自润滑复合材料,研究了CaF₂添加量对复合材料微观结构、力学性能及摩擦磨损性能的影响.结果表明:Ni-Mo-Y-CaF₂复合材料的组织均匀致密,复合材料的密度、硬度及屈服强度随CaF₂添加量的增加呈下降趋势.温度对复合材料的摩擦磨损性能有显著影响.在室温至800 ℃,复合材料的平均摩擦系数随温度的增加先降低,在400~600 ℃略微增加,随后再次降低;平均磨损率随着温度的增加先增加后又降低, 400 ℃时平均磨损率最大.在室温时,Ni-Mo-Y-10CaF₂复合材料的平均磨损率最低,约为Ni-Mo-Y合金的1/5;在800 ℃时,复合材料的磨损率均低于Ni-Mo-Y合金,磨损表面形成致密光滑的润滑膜,润滑膜主要由钼酸钙、钼酸镍及镍和钼的氧化物组成.

关键词: Ni-Mo-Y-CaF₂复合材料, 微观组织, 力学性能, 高温摩擦学性能

Abstract: Ni-Mo-Y-CaF₂ high temperature self-lubricating composites with different CaF₂ addition amounts were prepared using spark plasma sintering (SPS) technology. The microstructure, mechanical properties, friction and wear properties of the composites were studied. The results showed that the microstructure of Ni-Mo-Y-CaF₂ composites is uniform and dense, and the density, hardness and yield strength of the composites decrease with the amount of CaF₂ added increasing. Temperature significantly affects the friction and wear properties of the composites. From room temperature to 800 ℃, the average friction coefficient of the composites decreases initially with increasing temperature, slightly increases between 400 ℃ and 600 ℃, and then decreases again. The average wear rate increases initially with increasing temperature,and then decreases reaching a maximum at 400 ℃. At room temperature,the average wear rate of Ni-Mo-Y-10CaF₂ composite has the lowest average wear rate, about 1/5 of that of Ni-Mo-Y alloy. At 800 ℃, the wear rates of the composites are lower than that of the Ni-Mo-Y alloy. A dense and smooth lubricating film forms on the wear surface, mainly composed of calcium molybdate, nickel molybdate, and the oxides of nickel and molybdenum.

Key words: Ni-Mo-Y-CaF₂ composites, microstructure, mechanical property, high temperature tribological properties

中图分类号:

TG117.3

苏霄鹏, 金伟文, 杨贵荣, 陆龙, 王静波. Ni-Mo-Y-CaF₂高温自润滑复合材料的制备与摩擦学性能[J]. 兰州理工大学学报, 2024, 50(6): 1-10.

SU Xiao-peng, JIN Wei-wen, YANG Gui-rong, LU Long, WANG Jing-bo. Preparation and tribological properties of Ni-Mo-Y-CaF₂ high temperature self-lubricating composites[J]. Journal of Lanzhou University of Technology, 2024, 50(6): 1-10.

参考文献

[1] 熊党生,李建亮.高温摩擦磨损与润滑[M].西安:西北工业大学出版社,2013.
[2] 王平,叶晓苇,曹均.高温核用自润滑关节轴承设计及分析[J].轴承,2017(10):19-22.
[3] LONGSON B.Lubrication of high temperature ceramic materials[J].Tribology International,1983,16:221-225.
[4] 王常川,王日初,彭超群,等.金属基固体自润滑复合材料的研究进展[J].中国有色金属学报,2012,22:1945-1955.
[5] 王庆年,隋忠祥,张明,等.国外某些金属基自润滑复合材料的开发与进展[J].摩擦学学报,1997(1):90-97.
[6] PETERSON M B,MURRAY S F,FLOREK J J.Consideration of lubricants for temperatures above 1 000 F[J].ASLE Transactions,1959,2(2):225-234.
[7] 石淼森.固体润滑材料[M].北京:化学工业出版社,2001.
[8] ZHANG Y S,HU L T,CHEN J M,et al.Lubrication behavior of Y-TZP/Al₂O₃/Mo nanocomposites at high temperature[J].Wear,2010,268:1091-1094.
[9] LIU E,WANG W,GAO Y,et al.Tribological properties of Ni-based self-lubricating composites with addition of silver and molybdenum disulfide[J].Tribology International,2013,57:235-241.
[10] HAN J S,JIA J H,LU J J,et al.High temperature tribological characteristics of Fe-Mo-based self-lubricating composites[J].Tribology Letters,2009,34:193-200.
[11] KONG L,ZHU S,BI Q,et al.Friction and wear behavior of self-lubricating ZrO₂ (Y₂O₃)-CaF₂-Mo-graphite composite from 20 ℃ to 1000 ℃[J].Ceramics International,2014,40(7):10787-10792.
[12] LI J L,XIONG D S.Tribological properties of nickel-based self-lubricating composite at elevated temperature and counterface material selection[J].Wear,2008,265:533-539.
[13] 牛淑琴,朱家珮,欧阳锦林.几种高温自润滑复合材料的研制与性能研究[J].摩擦学学报,1995,15:324-332.
[14] ZHANG P,ZHAO G,WANG W,et al.Study on the mechanical and tribological properties and the mechanisms of Cr-freeNi-based self-lubricating composites at a wide temperature range[J].Metals,2020,10(2):268.
[15] 肖荣振,曹雪,安国升,等.宽温域LaF₃对镍基自润滑材料摩擦学性能的影响[J].稀有金属材料与工程,2020,49(1):267-273.
[16] 甄金明,李斐,朱圣宇,等.Ti对镍基高温自润滑复合材料力学和摩擦学性能的影响[J].摩擦学学报,2014,34:586-591.
[17] 李珍,张亚丽,周健松,等.Ni-Mo基高温自润滑复合材料摩擦学性能的研究[J].摩擦学学报,2018,38:161-169.
[18] 马燕合.我国稀土应用开发现状及其展望[J].材料导报,2000,14:3-5.
[19] 范景莲.钨合金及其制备新技术[M].北京:冶金工业出版社,2006.
[20] BRIONES F,SERIACOPI V,MARTIÍNEZ C,et al.The effects of pressure and pressure routes on the microstructural evolution and mechanical properties of sintered copper via SPS[J].Journal of Materials Research and Technology,2023,25:2455-2470.

Ni-Mo-Y-CaF₂高温自润滑复合材料的制备与摩擦学性能

Preparation and tribological properties of Ni-Mo-Y-CaF₂ high temperature self-lubricating composites

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