累积叠轧Al/Cu复合板界面反应层核-壳结构形成机制

兰州理工大学学报 ›› 2020, Vol. 46 ›› Issue (1): 1-6.

• 材料科学与工程 • 下一篇

累积叠轧Al/Cu复合板界面反应层核-壳结构形成机制

陈剑虹^1,2, 于洋泊¹, 张晓波^1,2

1.兰州理工大学材料科学与工程学院, 甘肃兰州 730050;
2.兰州理工大学有色金属先进加工与再利用省部共建国家重点实验室, 甘肃兰州 730050

收稿日期:2019-04-15 出版日期:2020-02-28 发布日期:2020-06-23
作者简介:陈剑虹(1937-),男,浙江杭州人,教授,博导.
基金资助:
国家自然科学基金(51601084)

Formation mechanism of core-shell structure in interface reaction layer of accumulative pack-rolled Al/Cu composite sheet

CHEN Jian-hong^1,2, YU Yang-bo¹, ZHANG Xiao-bo^1,2

1. School of Materials Science and Engineering, Lanzhou Univ. of Tech. , Lanzhou 730050, China;
2. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou Univ. of Tech. , Lanzhou 730050, China

Received:2019-04-15 Online:2020-02-28 Published:2020-06-23

摘要/Abstract

摘要： 采用累积叠轧(ARB)结合多次退火处理制备了Al/Cu复合板,重点研究了Al/Cu界面反应层核-壳结构形成机制. 结果表明:Al/Cu界面反应层的形成主要依赖于退火过程中铜原子在界面处的扩散,反应产物包括Al₂Cu、AlCu、Al₄Cu₉. 轧制变形致使反应层破碎并在基体中均匀分布,轧后退火处理导致新的反应层不断形成.最终经多次叠轧及退火处理,原始铜板材全部转变为椭球状具有核-壳结构的Al/Cu金属间化合物颗粒. 8道次复合板抗拉强度最高,达到176.8 MPa,是退火态1060抗拉强度的1.74倍;0道次复合板延伸率较好,主要是Al/Cu界面分层后铝层均匀塑性变形,应力缓慢释放所致.

关键词: 累积叠轧(ARB), Al/Cu复合板, 界面反应层, 核-壳结构

Abstract: The Al/Cu composite sheet was fabricated by means of accumulative pack-roll (ARB) incorporated with multiple annealing treatment and the core-shell structure formation mechanism of Al/Cu interfacial reaction layer was emphatically investigated. The result showed that atomic diffusion of copper at Al/Cu interface during annealing would play a key role in the formation of Al/Cu interfacial reaction layer and the resultants would include intermetallic compounds Al₂Cu, AlCu and Al₄Cu₉. The rolling deformation would make the reaction layer broken and distributed uniformly the matrix. The annealing treatment after rolling would lead to continuous formation of new interface reaction layer. Finally, after multiple pack-rolled pass and annealing treatment, the entire primary copper sheets would be transformed into axiolitic Al/Cu intermetallic compound particles with core-shell structure. The composite sheet after eight ARB passes would have highest ultimate tensile strength (UTS) of 176.8 MPa which would be 1.74 times of that of annealed 1060. The elongation of composite sheet without rolling would be better; this was basically due to that the aluminium layer would deform plastically and uniformly after Al/Cu interface delamination and the stress would slowly be released.

Key words: accumulative pack roll bonding (ARB), Al/Cu composite sheet, interface reaction layer, core-shell structure

中图分类号:

TG339

陈剑虹, 于洋泊, 张晓波. 累积叠轧Al/Cu复合板界面反应层核-壳结构形成机制[J]. 兰州理工大学学报, 2020, 46(1): 1-6.

CHEN Jian-hong, YU Yang-bo, ZHANG Xiao-bo. Formation mechanism of core-shell structure in interface reaction layer of accumulative pack-rolled Al/Cu composite sheet[J]. Journal of Lanzhou University of Technology, 2020, 46(1): 1-6.

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累积叠轧Al/Cu复合板界面反应层核-壳结构形成机制

Formation mechanism of core-shell structure in interface reaction layer of accumulative pack-rolled Al/Cu composite sheet

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