HPEI接枝改性PAN/GO-PAA静电纺纳米复合纤维膜对Au(Ⅲ)的吸附

摘要/Abstract

摘要： 以丙烯酸(AA)为单体,过氧化苯甲酰(BPO)为引发剂,通过原位聚合法,在氧化石墨烯(GO)表面包覆聚丙烯酸(PAA),得到GO-PAA纳米复合物.将GO-PAA纳米复合物分散在聚丙烯腈(PAN)基体中,利用静电纺丝技术得到PAN/GO-PAA静电纺纳米复合纤维膜.利用化学接枝反应在PAN/GO-PAA静电纺纳米复合纤维膜表面接枝超支化聚乙烯亚胺(HPEI),构筑HPEI-g-PAN/GO-PAA静电纺纳米复合纤维膜.研究了HPEI-g-PAN/GO-PAA静电纺纳米复合纤维膜对Au(Ⅲ)的吸附性能.结果表明:HPEI-g-PAN/GO-PAA静电纺纳米复合纤维膜对Au(Ⅲ)的最大吸附量为1 808.60 mg·g^－1,在吸附过程中,部分Au(Ⅲ)被还原为片状和不规则颗粒状的Au单质.在共存离子体系中,HPEI-g-PAN/GO-PAA对Au(Ⅲ)具有较好的吸附选择性.

关键词: 超支化聚乙烯亚胺, 聚丙烯腈, 静电纺纳米复合纤维膜, 吸附, Au(Ⅲ)

Abstract: Using acrylic acid (AA) as monomer and benzoyl peroxide (BPO) as initiator, polyacrylic acid (PAA) was coated on the surface of graphene oxide (GO) by in-situ polymerization to obtain GO-PAA nanocomposites. The GO-PAA nanocomposites were dispersed in polyacrylonitrile (PAN) matrix, and PAN/GO-PAA electrospun nanocomposite fibrous membranes were obtained by electrospinning technology. HPEI-g-PAN/GO-PAA electrospun nanocomposite fibrous membranes were fabricated by grafting hyperbranched polyethyleneimine (HPEI) on the surface of PAN/GO-PAA electrospun nanocomposite fibrous membranes with chemical grafting reaction. The adsorption performance of HPEI-g-PAN/GO-PAA electrospun nanocomposite fibrous membranes for Au(Ⅲ) was studied by batch experiments. The results showed that the maximum adsorption capacity of HPEI-g-PAN/GO-PAA electrospun nanocomposite fibrous membranes for Au(Ⅲ) was 1 808.60 mg·g^－1. During the adsorption process, partial Au(Ⅲ) was reduced to flake and irregularly granular Au elemental. HPEI-g-PAN/GO-PAA electrospun nanocomposite fibrous membranes had good adsorption selectivity for Au(Ⅲ) in the coexisting ionic system.

Key words: hyperbranched polyethyleneimine, polyacrylonitrile, electrospun nanocomposite fibrous membranes, adsorption, Au(Ⅲ)

中图分类号:

TB383.2

李晓华, 马应霞, 杨海军, 孟文丽, 钟小妹. HPEI接枝改性PAN/GO-PAA静电纺纳米复合纤维膜对Au(Ⅲ)的吸附[J]. 兰州理工大学学报, 2022, 48(6): 16-27.

LI Xiao-hua, MA Ying-xia, YANG Hai-jun, MENG Wen-li, ZHONG Xiao-mei. HPEI graft modification PAN/GO-PAA electrospun nanocomposite fibrous membranes for adsorption of Au(Ⅲ)[J]. Journal of Lanzhou University of Technology, 2022, 48(6): 16-27.

参考文献

[1] PARK S I,KWAK I S,MIN A B,et al.Recovery of gold as a type of porous fiber by using biosorption followed by incineration [J].Bioresource Technology,2012,104:208-214.
[2] ZENG M,ZHANG T A,LV G Z,et al.Adsorption of Au(Ⅲ) ions on xanthated crosslinked chitosan resin in hydrochloric acid medium [J].Rare Metals,2021,40:743-748.
[3] WU Y,FANG Q,YI X,et al.Recovery of gold from hydrometallurgical leaching solution of electronic waste via spontaneous reduction by polyaniline [J].Progress in Natural Science:Materials International,2017,27(4):514-519.
[4] CHEN L,TANG J,ZHANG X,et al.A novel benzothiazole modified chitosan with excellent adsorption capacity for Au(Ⅲ) in aqueous solutions [J].International Journal of Biological Macromolecules,2021,193:1918-1926.
[5] 韦会鸽,李岱原,马俊辉,等.玉米芯基生物炭的制备及其吸附性能 [J].兰州理工大学学报,2020,46(6):77-84.
[6] 何玲,秦兴文,冯玉洁,等.静电纺丝法制备YAG-ZrO₂复合纳米纤维 [J].兰州理工大学学报,2020,46(3):28-33.
[7] HOSSAINI Z S S,KHANLATI S,MOHAMMADI T.Hydrous metal oxide incorporated polyacrylonitrile-based nanocomposite membranes for Cu(II) ions removal [J].Separation and Purification Technology,2019,213:151-161.
[8] QUAN F,BI S,WANG X,et al.Surface modification of electrospun PAN nanofibers and its application for adsorption of lead ions [J].Journal of Fiber Bioengineering and Informatics,2011,4(4):383-388.
[9] JIANG Y J,WANG F,WANG X L,et al.Preparation of modified polyacrylonitrile nanofibers by electrospinning and adsorption of U(Ⅵ) [J].Journal of Nuclear and Radiochemistry,2020,42(5):397-407.
[10] CHEN Y,JIANG L.A core-shell amidoxime electrospun nanofiber affinity membrane for rapid recovery Au (Ⅲ) from water [J].Chinese Journal of Chemical Engineering,2022,42:424-436.
[11] 杜志辉,贾铭椿,王晓伟,等.聚丙烯腈基钛酸钾球形复合吸附剂的制备及其对Sr²⁺的吸附性能研究 [J].原子能科学技术,2019,53(8):1359-1366.
[12] HAIDER S,BINAGAG,F F,HAIDER A,et al.Fabrication of the diethylenetriamine grafted polyacrylonitrile electrospun nanofibers membrane for the aqueous removal of cationic dyes [J].Science of Advanced Materials,2015,7(2):309-318.
[13] 侯新刚,张文鹏,姜丽丽,等.GO/SWCNTs分子筛膜制备及其分离CO₂和N₂性能 [J].兰州理工大学学报,2019,45(6):22-27.
[14] HUANG Y L,GUO D.Preparation of CNT-PAN composite nanofiber membrane and its adsorption capability for methylene blue [J].Technology of Water Treatment,2018,44(1):71-75.
[15] 李佳慧.GO/PAN纳米纤维膜功能化改性及抗微生物污染性能研究 [D].天津:天津工业大学,2019.
[16] 陈薇.石墨烯气凝胶及其复合材料的制备与电化学性能研究 [D].深圳:深圳大学,2017.
[17] 谢标明,朱和康,杨越,等.聚丙烯酸/氧化石墨烯复合水凝胶制备及对亚甲基蓝吸附 [J].精细化工,2018,35(1):108-117.
[18] 杨春风,李勰,张颖鑫,等.原位聚合法制备聚丙烯酸修饰的ZnS量子点 [J].复合材料学报,2020,37(9):2258-2264.
[19] LIU J,JIN C,WANG C.Hyperbranched thiourea-grafted electrospun polyacrylonitrile fibers for efficient and selective gold recovery [J].Journal of Colloid and Interface Science,2020,561:449-458.
[20] WANG N,LIU Y,LI Y,et al.Fluorescent and colorimetric sensor for Cu²⁺ ion based on formaldehyde modified hyperbranched polyethylenimine capped gold nanoparticles [J].Sensors and Actuators B:Chemical,2018,255:78-86.
[21] 隋春红,龚剑,毛晓倩,等.静电纺PVA/PEI纳米纤维对不同价态铬离子吸附机制 [J].分子科学学报,2019,35(2):155-162.
[22] MA Y,JIN P,LEI W,et al.One-pot method fabrication of superparamagnetic sulfonated polystyrene/Fe₃O₄/graphene oxide micro-nano composites [J].Journal of Porous Materials,2018,25(5):1447-1453.
[23] YAN L K,ZHANG G,ZHANG L,et al.Robust construction of underwater superoleophobic CNTs/nanoparticles multifunctional hybrid membranes via interception effect for oily wastewater purification [J].Journal of Membrane Science,2019,569(1):32-40.
[24] ZHAO R,LI X,SUN B,et al.Branched polyethylenimine grafted electrospun polyacrylonitrile fiber membrane:a novel and effective adsorbent for Cr(Ⅵ) remediation in wastewater [J].Journal of Materials Chemistry A,2017,5(3):1133-1144.
[25] ZHAO R,LI Y,LI X,et al.Facile hydrothermal synthesis of branched polyethylenimine grafted electrospun polyacrylonitrile fiber membrane as a highly efficient and reusable bilirubin adsorbent in hemoperfusion [J].Journal of Colloid and Interface Science,2018,514:675-685.
[26] FRYCZKOWSKA B,BINIAS D,SLUSARCZYK C,et al.Influence of graphene oxide on the properties of composite polyacrylonitrile membranes [J].Desalination and Water Treatment,2017,81:67-79.
[27] HOSSEINI S M,SHAHROUSVAND M,SHOJAEI S,et al.Preparation of superabsorbent eco-friendly semi-interpenetrating network based on cross-linked poly acrylic acid/xanthan gum/graphene oxide (PAA/XG/GO):characterization and dye removal ability [J].International Journal of Biological Macromolecules,2020,152:884-893.
[28] KONG W J,YUE Q Y,LI Q,et al.Adsorption of Cd²⁺ on GO/PAA hydrogel and preliminary recycle to GO/PAA-CdS as efficient photocatalyst [J].Science of the Total Environment,2019,668(10):1165-1174.
[29] KUANG Y Z,HE H,CHEN S X,et al.Adsorption behavior of CO₂ on amine-functionalized polyacrylonitrile fiber [J].Adsorption-Journal of the International Adsorption Society,2019,25(4):693-701.
[30] MAŞLAKCI N N.Development and characterization of drug-loaded PVP/PAN/Gr electrospun fibers for drug delivery systems [J].Chemistry Select,2021,6(10):2548-2560.
[31] BIAN J,LI Y,ZHU C,et al.Graphene oxide-hyperbranched polyethyleneimine fabricated and stabilized AuNPs nanocomposites for colorimetric detection of silver ions based on a non-aggregation mechanism [J].Chem Nano Mat,2020,7(1):85-94.
[32] YANG Y W,LUO S,GUO S L,et al.Synthesis of Au nanoparticles supported on mesoporous N-doped carbon and its high catalytic activity towards hydrogenation of 4-nitrophenol to 4-aminophenol [J].International Journal of Hydrogen Energy,2017,42:29236-29243.
[33] LIU F,WANG S,CHEN S.Adsorption behavior of Au(Ⅲ) and Pd(Ⅱ) on persimmon tannin functionalized viscose fiber and the mechanism [J].Int J Biol Macromol,2020,152:1242-1251.
[34] LIU J,LIU M,CHEN S,et al.Conversion of Au(Ⅲ)-polluted waste eggshell into functional CaO/Au nanocatalyst for biodiesel production [J].Green Energy & Environment,2022,7(2):352-359.
[35] NIU H,YANG H,TONG L.Adsorption behaviors of Au(Ⅲ) onto humic acid extracted from gold ore:Adsorptive kinetics,isotherm and mechanism [J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,630:127442.
[36] YANG X,PAN Q,AO Y,et al.Facile preparation of L-cysteine-modified cellulose microspheres as a low-cost adsorbent for selective and efficient adsorption of Au(Ⅲ) from the aqueous solution [J].Environmental Science and Pollution Research,2020,27(30):38334-38343.
[37] LUO S L,XU X L,ZHOU G Y,et al.Amino siloxane oligomer-linked graphene oxide as an efficientadsorbent for removal of Pb(Ⅱ) from wastewater [J].Journal of Hazardous Materials,2014,274:145-155.
[38] MIN M H,SHEN L D,HONG G S,et al.Micro-nano structure poly(ether sulfones)/poly(ethyleneimine) nanofibrous affinity membranes for adsorption of anionic dyes and heavy metal ions in aqueous solution [J].Chemical Engineering Journal,2012,197:88-100.
[39] BORREGO M,JE MARTIN-ALFONSO,MC SANCHEZ,et al.Electrospun lignin-PVP nanofibers and their ability for structuring oil [J].International Journal of Biological Macromolecules,2021,180:212-221.
[40] WANG J,WANG X,ZHANG P,et al.Thiol-functionalized electrospun polyacrylonitrile nanofibrous membrane for highly efficient removal of mercury ions [J].Chemical Engineering Research and Design,2016,113:1-8.
[41] 吕大雷,范玮,冯宁川.黄芪废渣活性炭的制备及其对Cu²⁺和Cd²⁺的吸附特性 [J].兰州理工大学学报,2019,45(1):73-77.
[42] SUN Y K,DING Y Q,ZHOU W W,et al.Synthesis and selective Au(Ⅲ) adsorption of ureido polymers containing large repeating rings [J].ACS Omega,2021,6:28004-28011.
[43] GAO F,GAO,W H,FENG X Q,et al.Design and preparation of novel functional resin D301-g-polyvinylimidazole for recovering Au(Ⅲ) from aqueous solution[J].Desalination and Water Treatment,2021,220:232-240.
[44] XU W P,YAO S M,JI X R,et al.Effective recovery of Au from low-concentration solutions by a self-synthesized mesoporous resin modified by dimethylamine [J].Industrial & Engineering Chemister Research,2022,61(7):2894-2903.
[45] DARROUDI M,ZIARANI G M,GHASEMI J B,et al.SBA-ionic liquid as an efficient adsorbent of palladium,silver,and gold ions [J].Journal of the Iranian Chemical Society,2021,19(1):247-255.
[46] WANG S,WANG H,TANG J L,et al.Chitosan functionalized with N,N-(2-aminoethyl)pyridinedicarboxamide for selective adsorption of gold ions from wastewater [J].International Journal of Biological Macromolecules,2022,194:781-789.
[47] WANG S H,CHANG F C.Cu(II) and Au(Ⅲ) recovery with electrospun lignosulfonate CO₂-activated carbon fiber [J].International Journal of Biological Macromolecules,2022,203:505-514.