兰州理工大学学报 ›› 2021, Vol. 47 ›› Issue (1): 11-15.

• 材料科学与工程 • 上一篇    下一篇

稀土Y对Al-8%Mn合金微观组织和性能的影响

刘建军, 吕姝玥, 曾宝根, 兰晔峰, 李庆林   

  1. 兰州理工大学 材料科学与工程学院, 甘肃 兰州 730050
  • 收稿日期:2020-05-22 出版日期:2021-02-28 发布日期:2021-03-11
  • 作者简介:刘建军(1979-),男,山东临邑人,博士生,工程师.
  • 基金资助:
    国家自然科学基金(51561021)

Effect of rare earth yttrium addition on the microstructure and properties of Al-8%Mn alloy

LIU Jian-jun, LÜ Shu-yue, ZENG Bao-gen, LAN Ye-feng, LI Qing-lin   

  1. College of Materials Science and Engineering, Lanzhou Univ. of Tech., Lanzhou 730050, China
  • Received:2020-05-22 Online:2021-02-28 Published:2021-03-11

摘要: 采用光学显微镜、扫描电子显微镜、电子探针和X射线衍射仪,研究了Al-8%Mn合金熔体中添加稀土Y质量分数对合金微观组织的作用机制,并分析了稀土Y添加量对合金力学性能和耐蚀性能的影响规律.结果表明:稀土Y能有效细化Al-8%Mn合金中的Al6Mn化合物相和α-Al相.当Y的添加质量分数为3%时,细化效果最佳,使Al6Mn相的形貌由粗大板条状和块状转变为细小块状,平均尺寸由未细化前的67.4 μm减小到36.5 μm,α-Al由粗大的柱状晶细化成等轴晶,其平均尺寸减小至48 μm.稀土Y添加后Al-8%Mn合金的抗拉强度和延伸率分别由组织未细化前的126 MPa和1.47%增加到141 MPa和2.26%,分别提高了12.0%和76.9%.此外,在30 g NaCl+10 mL HCl+1 L H2O溶液中的腐蚀研究表明,随着Al-8%Mn合金中稀土Y添加量的增加,合金的抗蚀性能逐渐变差.

关键词: Al-Mn合金, Al6Mn, α-Al, 力学性能, 抗蚀性能

Abstract: The optical microscope, SEM, electron probe and XRD were used respectively in this research to investigate the dominant mechanism of rare earth Y added in Al-8%Mn alloy melt on microstructure of the alloy. The effect of amount of rare earth Y on the mechanical properties and corrosion resistance of the alloy was analyzed as well. Our results show clearly that the addition of rare earth Y can refine Al6Mn compounds and α-Al phases in Al-8%Mn alloy during alloy solidification. Moreover, after adding 3wt.% Y to Al-8%Mn alloy melt, the refining efficiency caused by Al6Mn and α-Al phases is most significant. The morphology of Al6Mn phases changes from coarse lath to small piece and blocky, and the average size of Al6Mn reduces from 67.4 μm to 36.5 μm. Hence, the morphology of α-Al phase transfers from coarse columnar crystal to equiaxed crystal, and the average size decreases to 48 μm when 3wt.%Y is added to Al-8%Mn alloy melt. Both the ultimate tensile strength and elongation of Al-8Mn-3wt.%Y alloy are improved up to 141.37 MPa and 2.26% respectively. In the end, the addition of rare earth reduces the intergranular corrosion resistance of the alloy in etching solution (30 g NaCl+10 mL HCl+1 L H2O).

Key words: Al-Mn alloys, Al6Mn, α-Al, mechanical properties, corrosion resistance

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