Electrochemical properties of coral-like nickel-cobalt bimetallic oxide-doped carbon nanohybrid materials

Abstract

Abstract: Metal-organic frameworks (MOFs) have received attention as supercapacitor electrode materials due to their large specific surface area, adjustable pore size and abundant redox sites. However, the specific capacitance of MOFs limits their further application. In this paper, employing three-dimensional (3D) spiny cypress-like Ni/Co-MOF as precursors obtained by hydrothermal method using Ni (NO₃)₂·6H₂O and Co (NO₃)₂·6H₂O as the metal ion sources and terephthalic acid as the organic ligand, a series of coral-like nickel-cobalt bimetallic oxide-doped carbon nanohybrid materials (NCPO/C) were prepared in an air atmosphere by regulatingthe heat treatment temperature and isothermal time, and their electrochemical properties as supercapacitor electrode materials were investigated. The results showed that the coral-like NCPO/C sample obtained byheating the 3D spiny cypress-like Ni/Co-MOF precursor at 280 ℃ for 1 h in air atmosphere, has the best electrochemical performance as electrode materials. When the current density expand from 0.5 A·g^－1 to 5.0 A·g^－1, the specific capacitance of NCPO/C decrease from 852.5 C·g^－1 to 720.0 C·g^－1, and the capacitance retention 84.5%.

Key words: metal-organic framework materials, metal oxides, supercapacitors, electrode materials, electrochemical performance

CLC Number:

O646

MA Ying-xia, LEI Lei, LIU Bing-lu, KANG Xiao-ya, RAN Fen. Electrochemical properties of coral-like nickel-cobalt bimetallic oxide-doped carbon nanohybrid materials[J]. Journal of Lanzhou University of Technology, 2024, 50(6): 17-27.

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URL: https://journal.lut.edu.cn/EN/

https://journal.lut.edu.cn/EN/Y2024/V50/I6/17

References

[1] ZUHRI F U,DIANTORO M,SURYANTI L,et al.ZnO-FC-NiCo MOF for prospective supercapacitor materials[J].Materials Today: Proceedings,2021,44(11):3385-3389.
[2] 冉奋,孔令斌,罗永春,等.化学氧化法合成超级电容器电极用聚吡咯及其工艺优化[J].兰州理工大学学报,2007,33(6):27-32.
[3] GHOLIPOUR R H,SOLEIMAINI M,NADERI H R.Application of Ni/Co-based metal-organic frameworks (MOFs) as an advanced electrode material for supercapacitors[J].New Journal of Chemistry,2016,40(11):9187-9193.
[4] GAO S,SUI Y,WEI F,et al.Dandelion-like nickel/cobalt metal-organic framework based electrode materials for high performance supercapacitors[J].Journal of Colloid and Interface Science,2018,531:83-90.
[5] ZHAO S,ZENG L,CHENG G,et al.Ni/Co-based metal-organic frameworks as electrode material for high performance supercapacitors[J].Chinese Chemical Letters,2019,30(3):605-609.
[6] ZHANG H,WANG J,SUN Y,et al.Wire spherical-shaped Co-MOF electrode materials for high-performance all-solid-state flexible asymmetric supercapacitor device[J].Journal of Alloys and Compounds,2021,879:160423.
[7] WANG J W,MA Y X,KANG X Y,et al.A novel moss-like 3D Ni-MOF for high performance supercapacitor electrode material[J].Journal of Solid State Chemistry,2022,309:122994.
[8] XIA H,ZHANG J,YANG Z,et al.2D MOF nanoflake-assembled spherical microstructures for enhanced supercapacitor and electrocatalysis performances[J].Nano-Micro Letters,2017,9(4):1-11.
[9] LIU X,ZHANG X,LIU R,et al.A Ni-doped Mn-MOF decorated on Ni-foam as an electrode for high-performance supercapacitors[J].Journal of Nanoparticle Research,2022,24(2):1-10.
[10] ZHANG B,SONG S,LI W,et al.Asymmetric supercapacitors with high energy density and high specific capacitance based on Ni-Co-Mn multiphase metal structure MOF[J].Ionics,2021,27(8):3553-3566.
[11] HANG X,ZHAO J,XUE Y,et al.Synergistic effect of Co/Ni bimetallic metal-organic nanostructures for enhanced electrochemical energy storage[J].Journal of Colloid and Interface Science,2022,628:389-396.
[12] YE C,QIN Q,LIU J,et al.Coordination derived stable Ni-Co MOFs for foldable all-solid-state supercapacitors with high specific energy[J].Journal of Materials Chemistry A,2019,7(9):4998-5008.
[13] 牛晓勤,康小雅,马应霞,等.新型球状Ni/Co-MOFs电极材料的构筑及电化学性能研究[J].材料导报,2022,36(14):163-169.
[14] KANG X Y,WANG J W,MA Y X,et al.3D juniperus sabina-like Ni/Co metal-organic framework as an enhanced electrode material for supercapacitors[J].Journal of Solid State Chemistry,2022,310:123056.
[15] XU X,YANG J,HONG Y,et al.Nitrate precursor driven high performance Ni/Co-MOF nanosheets for supercapacitors[J].ACS Applied Nano Materials,2022,5(6):8382-8392.
[16] ZHANG B,SONG S,LI W,et al.Asymmetric supercapacitors with high energy density and high specific capacitance based on Ni-Co-Mn multiphase metal structure MOF[J].Ionics,2021,27(8):3553-3566.
[17] ZHANG X T,LU Q F,LIU H,et al.Nature-inspired design of NiS/carbon microspheres for high-performance hybrid supercapacitors[J].Applied Surface Science,2020,528:146976.
[18] WAHEED A,KAZI I W,MANZAR M S,et al.Ultrahigh and efficient removal of Methyl orange,eriochrom Black T and Acid Blue 92 by triazine based cross-linked polyamine resin:Synthesis,isotherm and kinetic studies[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2020,607:125472.
[19] SHAIFUL B A M,OTHMAN S Z,MOHAMAD F M F,et al.Facile synthesis of Zr-based metal-organic gel(Zr-MOG) using “green” sol-gel approach[J].Surfaces and Interfaces,2021,27:101469.
[20] NIE X,KONG X,SELVAKUMARAN D,et al.Three-dimensional carbon-coated treelike Ni₃S₂ superstructures on a nickel foam as binder-free bifunctional electrodes[J].ACS Applied Materials & Interfaces,2018,10(42):36018-36027.
[21] RAJESH J A,PARK J H,VINH Q V H,et al.Rambutan-like cobalt nickel sulfide(CoNi₂S₄) hierarchitecture for high-performance symmetric aqueous supercapacitors[J].Journal of Industrial and Engineering Chemistry,2018,63:73-83.
[22] HE D,GAO Y,YAO Y,et al.Asymmetric supercapacitors based on hierarchically nanoporous carbon and ZnCo₂O₄ from a single biometallic metal-organic frameworks(Zn/Co-MOF)[J].Frontiers in Chemistry,2020,8:719.
[23] SONG S,MA X,ZHANG B,et al.Morphologies of thienyl based bimetallic metal-organic frameworks controlled by solvents for high specific capacitance supercapacitor[J].Journal of Energy Storage,2022,47:103627.